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Potassium tetraperoxochromate(V) : ウィキペディア英語版
Potassium tetraperoxochromate(V)

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Potassium peroxochromate, or potassium tetraperoxochromate(V), is an inorganic chemical having the chemical formula K3(). A crystalline ionic solid with a brown color, it is the potassium salt of tetraperoxochromate(V), one of the few examples of chromium in the +5 oxidation state.
==Preparation==

Potassium peroxochromate is prepared by reacting hydrogen peroxide with potassium chromate at low temperatures:
: 2 + 8 → 2 + 8
The intermediate tetraperoxochromate(VI) is reduced by hydrogen peroxide, forming tetraperoxochromate(V):〔(【引用サイトリンク】 Preparation, Structure and Vibrational Spectroscopy of Tetraperoxo Complexes of CrV+, VV+, NbV+ and TaV+ )〕〔

: 2 + 2 + → 2 + 2 +
Thus, the overall reaction is:
:2 + 9 + 2 → 2 + 10 +
The compound decomposes spontaneously at higher temperatures.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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