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Potassium tetraperoxochromate(V) : ウィキペディア英語版 | Potassium tetraperoxochromate(V)
|Section2= |Section3= }} Potassium peroxochromate, or potassium tetraperoxochromate(V), is an inorganic chemical having the chemical formula K3(). A crystalline ionic solid with a brown color, it is the potassium salt of tetraperoxochromate(V), one of the few examples of chromium in the +5 oxidation state. ==Preparation==
Potassium peroxochromate is prepared by reacting hydrogen peroxide with potassium chromate at low temperatures: : 2 + 8 → 2 + 8 The intermediate tetraperoxochromate(VI) is reduced by hydrogen peroxide, forming tetraperoxochromate(V):〔(【引用サイトリンク】 Preparation, Structure and Vibrational Spectroscopy of Tetraperoxo Complexes of CrV+, VV+, NbV+ and TaV+ )〕〔 〕 : 2 + 2 + → 2 + 2 + Thus, the overall reaction is: :2 + 9 + 2 → 2 + 10 + The compound decomposes spontaneously at higher temperatures.
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